Product ID:03731 BRIGHT ORANGE UPSIDE DOWN MARKING PAINTS-2
MSDS Date:02/01/1995
FSC:8010
NIIN:00F053052
MSDS Number: CDQZC

SHERWIN WILLIAMS CO THE SPECIALTY DIV

31500 SOLON ROAD
SOLON, OH 44139-5000
US

Emergency Phone: 800-777-2966/216-292-7400

Info Phone: 800-777-2966/800-247-3266

Cage: 54626

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

PROPANE (DIMETHYLMETHANE) *96-4*

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 13%

OSHA PEL 1000 PPM

ACGIH TLV: SIMPLE ASPHYXIANT

ISOBUTANE, 2-METHYLPROPANE

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: 13%

OSHA PEL 1800 MG/CUM

ACGIH TLV: 1000 PPM

ISOPARAFFINIC HYDROCARBONS (NAPHTHA PETROLEUM),

CAS: 64742-48-9

Fraction By Weight: 7-12%

TOLUENE (IARC CARC- GROUP 3) *96-4*

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 11-49%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETONE; DIMETHYL KETONE; 2-PROPANONE *96-4*

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 21%

OSHA PEL 2400 MG/CUM

ACGIH TLV: 750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1), CALCIUM CARBONATE,

CAS: 471-34-1

RTECS: FF9335000

Fraction By Weight: 25%

Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & RESPIRATORY
SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION, DEATH. LEAD:
OVEREXPOSURE MAY RESULT IN DAMAGE TO BLOOD-FORMING, NERVOUS,
URINARY & RESPRODUCTIVE SYSTEM, EMBRYOTOXI C EFFECTS. HEXANE: MAY
CAUSE DAMAGE TO NERVE TISSUE OF THE ARMS & LEGS. (SEE SUPP)
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE,
DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING.
LEAD: IRRITABILITY, WEAKNESS, MUSCLE/JOINT PAINS.

First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM & QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH
W/LARGE AMOUNTS OF WATER FOR 15 MINS. INGESTION: NEVER GIVE
ANYTHING BY MOUTH IF UNCONSCIOUS. DON'T INDUCE VOMITING GIVE
SEVERAL GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:PMCC
Flash Point:<0F
Lower Limits:0.7
Upper Limits:12.8
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERRED. WATER MAY BE USED TO COOL CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. VAPORS WILL ACCUMULATE READILY & IGNITE
EXPLOSIVELY. HEAT/IGNITION COULD CAUSE CONTAINERS TO BURST.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.

Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/OPEN FLAME
& OTHER IGNITION SOURCES. USE APPROVED BONDING/GROUNDING
PROCEDURES. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DON'T PUNCTURE, INCINERATE/EXPOSE TO TEMPS >120F.
DURING USE & UNTIL ALL VAPORS ARE GONE; KEEP AREA VENTILATED. DON'T
SMOKE. DON'T TAKE INTERNALLY. AVOID BREATHING VAPOR/SPRAY MIST.
AVOID CONTACT W/SK IN & EYES. USE W/ADEQUATE VENTILATION.

Respiratory Protection:IF EXPOSURE CAN'T BE CONTROLLED LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE REPIRATOR APPROVED BY NIOSH/MSHA. WHEN
SANDING/ABRADING THE DRIED FILM, WEAR A DUST/ IST RESPIRATOR
APPROVED BY NIOSH/MSHA.
Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST: ACCEPTABLE IF
EXPOSURE IS MAINTAINED Protective Gloves:RECOMMENDED
Eye Protection:REQUIRED
Other Protective Equipment:SAFETY SPECTACLES W/UNPERFORATED SIDESHIELD.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS AFTER USING.
Supplemental Safety and Health
PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE ADVERSE EFFECTS TO THE
LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRODUCTIVE
SYSTEMS. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANEN T BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY INHALING THE CONTENTS CAN BE HARMFUL/FATAL.

Boiling Pt:B.P. Text:<0-395F
Vapor Density:>1
Volatile Org Content %:3
Evaporation Rate & Reference:FASTER THAN ETHER
Percent Volatiles by Volume:>75

Stability Indicator/Materials to Avoid:YES
PILOT LIGHTS, ELECTRIC TOOLS/APPLIANCES, RADIATORS, STOVES, HOT WATER
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, ELECTRICAL
EQUIPMENT, TEMPS >120F, SUNLIGHT & OTHER IGNITION SOURCES
Hazardous Decomposition Products:BY FIRE: CO, CO2, OXIDES OF METALS

Waste Disposal Methods:WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERMINE THE EPA HAZARDOUS WASTE NUMBERS. WASTE MUST BE TREATED
FOR EXTRACTABILITY. DON'T INCINERATE. DEPRESSURIZE CONTAINER.
DISPOSE OF IAW/LOCAL, STATE & FE DERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.